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\(n_{NaOH}=\dfrac{16.10\%}{40}=0,04\left(mol\right)\\ 2NaOH+SO_2\rightarrow Na_2SO_3+H_2O\\ NaOH+SO_2\rightarrow NaHSO_3\\ Đặt:n_{NaHSO_3}=a\left(mol\right);n_{Na_2SO_3}=1,5a\left(mol\right)\\ \Rightarrow n_{NaOH\left(tổng\right)}=3a+a=4a=0,04\left(mol\right)\\ \Leftrightarrow a=0,01\left(mol\right)\\ n_{SO_2\left(tổng\right)}=n_{Na_2SO_3}+n_{NaHSO_3}=2,5a=0,025\left(mol\right)\\ V_{SO_2\left(đktc\right)}=0,025.22,4=0,56\left(lít\right)\)
Dd B chứa NaOH.
PT: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Ta có: \(n_{NaCl}=\dfrac{4,68}{58,5}=0,08\left(mol\right)\)
Theo PT: \(n_{NaOH\left(80\left(g\right)dd\right)}=n_{NaCl}=0,08\left(mol\right)\)
\(\Rightarrow n_{NaOH\left(200\left(g\right)dd\right)}=\dfrac{0,08.200}{80}=0,2\left(mol\right)\)
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(\left\{{}\begin{matrix}23n_{Na}+62n_{Na_2O}=5,4\\n_{Na}+2n_{Na_2O}=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{Na}=0,1\left(mol\right)\\n_{Na_2O}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=\dfrac{1}{2}n_{Na}=0,05\left(mol\right)\)
Ta có: m dd B = mA + mH2O - mH2
⇒ 200 = 5,4 + mH2O - 0,05.2
⇒ mH2O = 194,7 (g)
Na2O + H2O → 2NaOH
1 1 2
0,1 0,2
a). nNa2O=\(\dfrac{6,2}{62}\)= 0,1(mol)
CM=\(\dfrac{n}{V}\)=\(\dfrac{0,1}{4}\)= 0,025M
b). Na2O + H2SO4 → Na2SO4 + H2O
1 1 1 1
0,1 0,1
mH2SO4= n.M = 0,1 . 98 = 9,8g
⇒mddH2SO4= mct=\(\dfrac{mct.100\%}{C\%}\)= \(\dfrac{9,8.100}{20}\)= 49(g).
nNaOH=0,2mol
a) PTHH: 2NaOH+H2SO4=> Na2SO4+2H2O
0,2=>0,1
=> V H2SO4=0,1:0,5=0,2l=200ml
b) 2NaOH+SO2=>Na2SO3+H2O
2/15=>1/15
NaOH+SO2=>NaHSO3
1/15=>1/15
=> VSO2=2.1/15.22,4=2,98l